Ja. Trogolo et K. Rajan, NEAR-SURFACE MODIFICATION OF SILICA STRUCTURE INDUCED BY CHEMICAL-MECHANICAL POLISHING, Journal of Materials Science, 29(17), 1994, pp. 4554-4558
Planarization of dielectric materials in multilevel devices has become
an important topic in recent years. Planarization achieved through ch
emical/mechanical polishing (CMP) is the foremost of the techniques av
ailable to provide an appropriate low-topography surface for accurate
lithography. In this study the effects of the planarization process on
deposited SiO2 films, a material to which CMP is frequently applied,
have been examined. The analysis, completed using transmission electro
n microscopy and Fourier-transform infrared spectroscopy, revealed evi
dence of chemical/structural modification of the SiO2 to 100-200 nm fr
om the polished surface and more heavily altered or deformed regions e
xtending to a few tens of nm in depth.