J. Navarro et al., ELECTROCHEMICAL-BEHAVIOR AND ELECTRICAL PERCOLATION IN GRAPHITE-EPOXYELECTRODES, Journal of Materials Science, 29(17), 1994, pp. 4604-4610
The electrochemical properties of mouldable graphite-epoxy composite e
lectrodes have been studied as a function of graphite content. The sha
pe of ferri-ferrocyanide voltammograms relates to the ratio of graphit
e and an adsorption process. The dielectric constant from spectroelect
rochemical impedance measurement of this composite electrode is maximu
m when the proportion of graphite is ca. 60 wt%. An electrochemical eq
uivalent circuit is proposed. The graphite-epoxy composite acts as a m
ulti-microelectrode near this proportion.