ALPHA-SELECTIVE CROSS-COUPLING REACTION OF ALLYLTRIFLUOROSILANES - REMARKABLE LIGAND EFFECT ON THE REGIOCHEMISTRY

Authors
HATANAKA Y GODA K HIYAMA T
Citation
Y. Hatanaka et al., ALPHA-SELECTIVE CROSS-COUPLING REACTION OF ALLYLTRIFLUOROSILANES - REMARKABLE LIGAND EFFECT ON THE REGIOCHEMISTRY, Tetrahedron letters, 35(35), 1994, pp. 6511-6514
Citations number
20
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
35
Issue
35
Year of publication
1994
Pages
6511 - 6514
Database
ISI
SICI code
0040-4039(1994)35:35<6511:ACROA->2.0.ZU;2-S
Abstract
The cross-coupling reaction of allyltrifluorosilanes with aryl halides or aryl triflates promoted by a fluoride salt takes place at the alph a-carbon of the allyltrifluorosilanes in the presence of a catalytic a mount of PdCl2[Ph(2)P(CH2)(n)PPh(2)] (n = 2, 3), giving allylic arenes with high regioselectivity.