N. Trendafilova et al., LOW-TEMPERATURE FOURIER-TRANSFORM INFRARED-SPECTRA OF TETRACHLOROZINCATE, TETRACHLORONICKELATE AND TETRACHLOROCUPRATE WITH DIFFERENT COUNTER IONS, Vibrational spectroscopy, 6(3), 1994, pp. 351-362
Room-temperature infrared (IR) and Raman and low-temperature (100 and
77 K) IR spectra of R2MCl4 have been recorded in the 4000-50 cm-1 freq
uency range. The metal ions Zn(II), Ni(II) and Cu(II) form a series of
increasing ionic radius, while the counter ions [Bu4N]+, [Et4N]+, Rb, and Cs+ reflect the order of decreasing bulkiness. According to the
IR and Raman spectra, the [ML4]2- units are a distorted tetrahedron, t
he distortion away from the tetrahedral structure increasing with the
increasing size of the counter ion. Additional splittings due to the v
ibration-electronic coupling (Jahn-Teller coupling) was observed for t
he Cu(II) and Ni(II) compounds.