The surface embrittlement phenomenon has been studied on a coated poly
mer by means of instrumented falling weight impact tests. The specimen
s are made of a ductile blend, used in the car industry, coated with a
double layer paint system composed of a primer and a top coat. The en
ergy absorbed during the impact test is correlated with the viscoelast
ic spectra and tensile properties of both the blend and paint system c
omponents. The viscoelasticity of the coating system is found to be th
e crucial parameter of the embrittlement. In the case of a brittle coa
ting its thickness must exceed a critical value to embrittle the subst
rate.