T. Michalowski et E. Gibas, APPLICABILITY OF NEW ALGORITHMS FOR DETERMINATION OF ACIDS, BASES, SALTS AND THEIR MIXTURES, Talanta, 41(8), 1994, pp. 1311-1317
Regression equations of the Pade type (PADE W, PADE 1/W) and equations
with Simms' constants involved (SIMMS 1/W) were applied for the deter
mination of internal parameters (i.e. concentrations, equilibrium cons
tants, activity coefficient of hydrogen ions) related to a titrand-tit
rant system with one- or two-component sample tested with the species
having acid-base properties. The parameters were searched according to
an iteration procedure (MINUITS computer program applied).