SPECTROPHOTOMETRIC STUDIES ON THE SOLVATOCHROMISM OF THE FE(CN)(2)(PHEN)(2) COMPLEX

Citation
M. Podsiadla et al., SPECTROPHOTOMETRIC STUDIES ON THE SOLVATOCHROMISM OF THE FE(CN)(2)(PHEN)(2) COMPLEX, Monatshefte fuer Chemie, 125(8-9), 1994, pp. 827-831
Citations number
10
Categorie Soggetti
Chemistry
Journal title
ISSN journal
00269247
Volume
125
Issue
8-9
Year of publication
1994
Pages
827 - 831
Database
ISI
SICI code
0026-9247(1994)125:8-9<827:SSOTSO>2.0.ZU;2-9
Abstract
The solvatochromic behaviour of bis-(cyano)-bis-(9,10-phenanthroline)- iron(II) has been reexamined spectrophotometrically in a series of 19 solvents including water, alcohols and dipolar. aprotic media. Satisfa ctory correlations between the wave numbers of the long-wavelength ban d and solvent acceptor numbers are obtained in all media; only values, for carboxylic acids deviate from the regression line.