SYNTHESIS AND PROPERTIES OF NOVEL FLUOROALKYLATED ALLYL ALCOHOL OLIGOMERS

Authors
SAWADA H TANBA K OUE M KAWASE T MITANI M MINOSHIMA Y NAKAJIMA H NISHIDA M MORIYA Y
Citation
H. Sawada et al., SYNTHESIS AND PROPERTIES OF NOVEL FLUOROALKYLATED ALLYL ALCOHOL OLIGOMERS, Polymer, 35(18), 1994, pp. 4028-4030
Citations number
10
Categorie Soggetti
Polymer Sciences
Journal title
Polymer → ACNP
ISSN journal
00323861
Volume
35
Issue
18
Year of publication
1994
Pages
4028 - 4030
Database
ISI
SICI code
0032-3861(1994)35:18<4028:SAPONF>2.0.ZU;2-E
Abstract
Allyl alcohol and allyl alcohol containing the polyoxyethylene unit we re found to react with fluoroalkanoyl peroxides to afford the correspo nding fluoroalkylated allyl alcohol oligomers via a radical process un der very mild conditions. In particular, fluoroalkylated allyl alcohol oligomers containing the polyoxyethylene unit were shown to be effect ive in reducing the surface tension of water, and to be applicable for new non-ionic fluorinated amphiphiles.