H. Lutgemeier et al., A MICROSCOPIC MODEL FOR THE DIFFERENT T-C(X) DEPENDENCE IN REBA(2)CU(3)O(6-SUPERCONDUCTORS CONTAINING DIFFERENT RE-IONS(X) HTC), Journal of low temperature physics, 105(3-4), 1996, pp. 693-698
Replacing Y in YBa2Cu3O6+x by the larger ions Nd or La increases the c
ritical oxygen content for the transition from antiferromagnetic to su
perconducting behavior from x = 0.4 to 0.6. From the analysis of the N
QR spectra of the Cu(1) sites at different x follows a change of the i
nteraction in the oxygen pairs connected by a Cu(1) ion from attractiv
e for Y to repulsive for La.