G. Teissedre et al., PHOTOAGEING OF POLYOLEFINS .1. PHOTOLYSIS OF LOW-MOLECULAR-WEIGHT HYDROPEROXIDE AT LAMBDA-GREATER-THAN-OR-EQUAL-TO-300 NM, Polymer degradation and stability, 45(1), 1994, pp. 145-153
The photolysis of a low molecular weight secondary hydroperoxide (3-hy
droperoxyhexane) at wavelength longer than 300 nm and in dodecane as s
olvent has been investigated by ESR, FTIR, GC/MS and C-13-NMR. Results
were compared with the photolytic decomposition of macromolecular sec
ondary hydroperoxides present in a pre-oxidized polyethylene.