W. Reichardt, CU-O BOND-STRETCHING VIBRATIONS IN YBA(2)CU(3)0(7) STUDIED BY INELASTIC NEUTRON-SCATTERING, Journal of low temperature physics, 105(3-4), 1996, pp. 807-812
Inelastic neutron experiments confirm the previously reported anomalou
s nature of the planar oxygen bond-stretching vibrations and furnish f
urther details. It is shown that the frequency of the linear breathing
mode is renormalized by 5 THz compared to insulating YBa2Cu3O6 Studie
s of the Cu1-apical O bond-stretching vibrations demonstrate that freq
uencies, line-widths and phonon intensities can well be understood wit
hin the framework of a harmonic lattice dynamical model. This rules ou
t predictions of a double well potential and strong anharmonitity for
this type of vibration.