There were realized two liquid-membrane electrodes using the simple co
mplex as well as the mixed complex of copper with quinoxaline-2,3 - di
thiol. There were determined the primary and secondary characteristics
of these electrodes as well as the selectivity constants for their pr
actical use to potentiometrically dose copper. There were brought into
relief the advantages of using mixed complex as electroactive species
in realizing ion-selective electrodes.