S. Blasser et al., IN-SITU HYDROGEN CHARGING OF THIN NB FILMS AND DEPTH PROFILING WITH THE H-1(N-15,ALPHA-GAMMA)C-12 NUCLEAR-REACTION, Nuclear instruments & methods in physics research. Section B, Beam interactions with materials and atoms, 85(1-4), 1994, pp. 24-27
The hydrogen concentration in Nb films in equilibrium with an external
H2-gas was measured by the N-15-NRA method using a differential pumpi
ng system. We find that the hydrogen solubility in films is reduced co
mpared to that of bulk samples. This can be explained by the clamping
of epitaxial films to the substrate. These first direct measurements o
f solubility curves for films are in disagreement with earlier investi
gations by other authors, who found - based on indirect concentration
determinations - an increased solubility in films. We think that the d
iscrepancy is due to incorrect concentration determinations in these e
arlier studies.