B. Brijs et al., SPUTTERING PHENOMENA OF COSI2 UNDER LOW-ENERGY OXYGEN BOMBARDMENT, Nuclear instruments & methods in physics research. Section B, Beam interactions with materials and atoms, 85(1-4), 1994, pp. 306-310
Sputter depth profiling with AES, XPS and SIMS suffers from sputter in
duced artifacts such as preferential sputtering, segregation phenomena
and recoil displacements. A combined in situ sputter RBS system has b
een used to study the sputter process into detail. In this work the be
am induced oxidation of CoSi2 during low energy oxygen irradiation is
investigated. The oxygen bombardment of CoSi2 offers a very complex be
havior as a function of dose where we first observe a gradual Co deple
tion subsequently followed by a replenishment of this depleted region.
Additional XPS and TEM analysis of the bombarded CoSi2 shows that the
transient behavior can be correlated with changes in oxidation and di
fferent phase formations.