LANTHANIDE COMPLEXES WITH ACETYLACETONATE AND 5-(4-HYDROXYPHENYL)-10,15,20-TRIPHENYLPORPHYRIN LIGANDS

Authors
LIU GF SHI TS LIU XX
Citation
Gf. Liu et al., LANTHANIDE COMPLEXES WITH ACETYLACETONATE AND 5-(4-HYDROXYPHENYL)-10,15,20-TRIPHENYLPORPHYRIN LIGANDS, Polyhedron, 13(15-16), 1994, pp. 2255-2258
Citations number
10
Categorie Soggetti
Chemistry Inorganic & Nuclear",Crystallography
Journal title
Polyhedron → ACNP
ISSN journal
02775387
Volume
13
Issue
15-16
Year of publication
1994
Pages
2255 - 2258
Database
ISI
SICI code
0277-5387(1994)13:15-16<2255:LCWAA5>2.0.ZU;2-0
Abstract
Lanthanide Complexes of acetylacetonate and 5-(4-hydroxyphenyl)-10,15, 20-triphenylporphyrin having the general formula Ln[HP(Ph)(3)P]acac (w here Ln = Ho, Tm, Yb, Lu; HP = 4-hydroxyphenyl; Ph = phenyl; Hacac = a cetylacetone) have been synthesized and characterized. A structure in which one 5-(4-hydroxyphenyl)-10,15,20-triphenylporphyrin is coordinat ed to a lanthanide ion in a tetradentate fashion, while one acetylacet onate is coordinated to the same metal in a bidentate fashion is propo sed.