SYNTHESIS AND CRYSTAL-STRUCTURE OF A NOVEL KEGGIN-TYPE ISOPOLYOXOMOLYBDATE [BU(4)N](6)[H3O](2)[MO13O40](2)

Authors
JIN XL TANG KL NI HH TANG YQ
Citation
Xl. Jin et al., SYNTHESIS AND CRYSTAL-STRUCTURE OF A NOVEL KEGGIN-TYPE ISOPOLYOXOMOLYBDATE [BU(4)N](6)[H3O](2)[MO13O40](2), Polyhedron, 13(15-16), 1994, pp. 2439-2441
Citations number
6
Categorie Soggetti
Chemistry Inorganic & Nuclear",Crystallography
Journal title
Polyhedron → ACNP
ISSN journal
02775387
Volume
13
Issue
15-16
Year of publication
1994
Pages
2439 - 2441
Database
ISI
SICI code
0277-5387(1994)13:15-16<2439:SACOAN>2.0.ZU;2-Y
Abstract
Solid-state reaction of (NH4)(6)Mo7O24.4H(2)O with Bu(4)NBr and NH2OH. HCl at low temperature yields an isopolyoxomolybdate [Bu(4)N](+)(6)[H3 O](+)(2)[Mo13O40](4-)(2), the structure of which has been determined b y X-ray crystallography. The title compound contains two [Mo13O40](4-) anions which have different symmetry. Both anions have Keggin-type st ructures with a molybdenum atom centre.