EVIDENCE FOR A ROLE OF CHARGE-TRANSFER COMPLEX AND ISOTOPE-SOLVENT EFFECT IN IODINATION OF PHENYLSILANE

Authors
POLA J TAYLOR R
Citation
J. Pola et R. Taylor, EVIDENCE FOR A ROLE OF CHARGE-TRANSFER COMPLEX AND ISOTOPE-SOLVENT EFFECT IN IODINATION OF PHENYLSILANE, Polyhedron, 13(15-16), 1994, pp. 2451-2453
Citations number
8
Categorie Soggetti
Chemistry Inorganic & Nuclear",Crystallography
Journal title
Polyhedron → ACNP
ISSN journal
02775387
Volume
13
Issue
15-16
Year of publication
1994
Pages
2451 - 2453
Database
ISI
SICI code
0277-5387(1994)13:15-16<2451:EFAROC>2.0.ZU;2-A
Abstract
UV-vis absorption spectra of mixtures of phenylsilane C6H5SiH3 and iod ine in solutions of CDCl3, CHCl3, CH2Cl2, CCl4, c-C6H12 and C6H14 indi cate that both iodination of phenylsilane and formation of charge-tran sfer complexes between the two components is strongly enhanced in pola r chlorohydrocarbons. A unique deuterium solvent effect on the positio n of the maximum absorption of the C-T complex is observed.