A BRIDGE-TWISTED BINUCLEAR SILVER(I) CRYPTATE

Authors
YU SY LUO QH SHEN MC ZHANG Z HUANG XY WU QJ
Citation
Sy. Yu et al., A BRIDGE-TWISTED BINUCLEAR SILVER(I) CRYPTATE, Polyhedron, 13(15-16), 1994, pp. 2467-2469
Citations number
11
Categorie Soggetti
Chemistry Inorganic & Nuclear",Crystallography
Journal title
Polyhedron → ACNP
ISSN journal
02775387
Volume
13
Issue
15-16
Year of publication
1994
Pages
2467 - 2469
Database
ISI
SICI code
0277-5387(1994)13:15-16<2467:ABBSC>2.0.ZU;2-I
Abstract
The binuclear silver(I) cryptate [Ag(2)L](ClO4)(2) (L = C48H66N8O6) wa s prepared by [2+3] Schiff base condensation of tris(3-aminopropyl)ami ne with 2,5-dimethoxy-1,3-phenylenedialdehyde in the presence of AgNO3 . Crystal structure determination shows the cryptate possesses a formu la C48H66N8O14Ag2Cl2. Each silver coordinates to three nitrogen atoms and has a slightly distorted trigonal environment. The coordinated ato ms form a sulphur chain.