UNUSUALLY FACILE OXATHIOACETAL TRANSFER-REACTION - AN EFFICIENT, HIGHLY SELECTIVE CATALYTIC DEPROTECTION PROTOCOL

Authors
RAVINDRANATHAN T CHAVAN SP VARGHESE JP DANTALE SW TEJWANI RB
Citation
T. Ravindranathan et al., UNUSUALLY FACILE OXATHIOACETAL TRANSFER-REACTION - AN EFFICIENT, HIGHLY SELECTIVE CATALYTIC DEPROTECTION PROTOCOL, Journal of the Chemical Society, Chemical Communications, (17), 1994, pp. 1937-1938
Citations number
12
Categorie Soggetti
Chemistry
Journal title
Journal of the Chemical Society, Chemical Communications → ACNP
ISSN journal
00224936
Issue
17
Year of publication
1994
Pages
1937 - 1938
Database
ISI
SICI code
0022-4936(1994):17<1937:UFOT-A>2.0.ZU;2-1
Abstract
CF(3)SO(3)SiMe(3)-catalysed one-to-one exchange of oxathioacetals to c arbonyl compounds in the presence of 4-nitrobenzaldehyde is performed efficiently at room temperature, the protocol developed provides selec tive and effective deprotection of oxathiolanes in the presence of thi oacetals.