A NEW KINETIC PATTERN FOR THE SUBSTITUTION-REACTIONS OF INORGANIC COMPLEXES - STUDIES ON [FE2S2CL4](2-)

Authors
HENDERSON RA OGLIEVE KE
Citation
Ra. Henderson et Ke. Oglieve, A NEW KINETIC PATTERN FOR THE SUBSTITUTION-REACTIONS OF INORGANIC COMPLEXES - STUDIES ON [FE2S2CL4](2-), Journal of the Chemical Society, Chemical Communications, (17), 1994, pp. 1961-1962
Citations number
8
Categorie Soggetti
Chemistry
Journal title
Journal of the Chemical Society, Chemical Communications → ACNP
ISSN journal
00224936
Issue
17
Year of publication
1994
Pages
1961 - 1962
Database
ISI
SICI code
0022-4936(1994):17<1961:ANKPFT>2.0.ZU;2-B
Abstract
Kinetic studies on the substitution reactions of [Fe2S2Cl3(NCMe)](-) w ith the nucleophiles L = Br- or RS(-) (R = Et or But) to form [Fe2S2Cl 3](2-) show that the rate of the reaction is inhibited by increasing t he concentration of the nucleophile; this is a consequence of L bindin g to the iron atom not undergoing substitution.