DEPENDENCE OF DEHYDROGENATION OF AMINES TOWARDS COORDINATION GEOMETRY- OXIDATION-PRODUCTS OF TRICYANO[DI(2-PYRIDYLMETHYL)AMINE]FERRATE FROM MER AND FAC ISOMERS

Authors
GOTO M KOGA N OHSE Y KUROSAKI H KOMATSU T KURODA Y
Citation
M. Goto et al., DEPENDENCE OF DEHYDROGENATION OF AMINES TOWARDS COORDINATION GEOMETRY- OXIDATION-PRODUCTS OF TRICYANO[DI(2-PYRIDYLMETHYL)AMINE]FERRATE FROM MER AND FAC ISOMERS, Journal of the Chemical Society, Chemical Communications, (17), 1994, pp. 2015-2016
Citations number
13
Categorie Soggetti
Chemistry
Journal title
Journal of the Chemical Society, Chemical Communications → ACNP
ISSN journal
00224936
Issue
17
Year of publication
1994
Pages
2015 - 2016
Database
ISI
SICI code
0022-4936(1994):17<2015:DODOAT>2.0.ZU;2-0
Abstract
Two geometrical isomers, mer- and fac-tricyano[di(2-pyridylmethyl)amin e]ferrate(II) give the iron(II) complex with dehydrogenated ligand and iron(III) complex with intact ligand, respectively, upon oxidation wi th (NH4)(2)SO4 or H2O2 at neutral pH, which is confirmed by electroche mical measurements.