Experiments have been conducted to study the nucleation of bainite at
interfaces between ceramic compounds and low-alloy steels. To facilita
te this, chemically pure mineral powders were pressure bonded to steel
samples. The resulting composite samples were then heat treated to in
duce transformation, and hence compare the transformation behaviour in
the vicinity of the ceramic/steel interface to that within the bulk o
f the steel. It is found that the minerals may be categorised into thr
ee groups, according to their observed efficacy in inducing the nuclea
tion of bainite.The dominant reason for the stimulation of bainite nuc
leation seems to be a chemical interaction between the mineral and the
steel. One noteable exception is TiO, which, within the limits of res
olution, appears to remain inert, and yet enhances bainite formation.