N. Costarramone et al., COMPETITIVE ADSORPTION AND ELECTROSORPTIO N OF ORGANIC-COMPOUNDS (CHLOROFORM, BENZOIC-ACID AND PHENOL) ON GRANULAR ACTIVATED CARBON, Environmental technology, 15(3), 1994, pp. 199-218
A study of the competitive adsorption of organic compounds onto granul
ar activated carbon was made with or without electrochemical polarisat
ion of the adsorbent. Chosen models were chloroform/benzoic acid and c
hloroform/phenol. Without polarisation the presence of a second compou
nd in the solution induces a, reduction of the adsorption of the first
one. A positive polarisation increases adsorption of chloroform, redu
cing those of phenol or benzoic acid. A negative polarisation has the
inverse effect. A molecular model is proposed to justify these phenome
na.