Mimicking the mammalian olfactory system by an array of twelve thickne
ss-shear-mode (TSM) acoustic wave sensors with different adsorptive ma
terials to form an artificial odour-sensing system has been investigat
ed. The adsorptive materials chosen include polyethylene glycol-20M, h
exadecyltriphenyl phosphonium iodide, N-(2hydroxylbenzyl) dodecylamine
, tween 65, dinonyl phthalate, polyethylene glycol 400-monostearate, e
poxy resin, tri-n-octylphosphinoxid, di-iso-octyl phthalate, polyethyl
ene glycol-6000, thionalid and dimethylpropaneldiol succinate. The fre
quency shift data obtained from the sensor array responding to the odo
urs originated from different groups of organic compounds such as keto
nes (acetone, butanone, acetophenone, cyclohexanone, and acetylacetone
), esters (methyl acetate, ethyl acetate, n-propyl acetate, and n-buty
l acetate), and aldehydes (formaldehyde, benzaldehyde, glyoxal and fur
fural) are transformed to relative values to compensate the effect of
the variation of the actual coating frequency shift, Delta f. The rela
tive frequency shift data matrices are subjected to modified principal
component analysis (MPCA) treatment with or without data preprocesssi
ng. The odours of different organic molecule samples are easily recogn
ized from the two-dimensional displays of the first two principal comp
onents. The discrimination of aromas originated from different essenti
al oils from France (Adoucissant TM663, Atlantic TM3387, and Spat Tacu
s TM5970) and different fruits such as apples, bananas, oranges, and p
ears is also possible.