A FRIEDLANDER APPROACH TO NOVEL 1,10-PHENANTHROLINES AND THEIR USE ASLIGANDS FOR RU(II) AND CU(I)

Authors
HUNG CY WANG TL SHI ZQ THUMMEL RP
Citation
Cy. Hung et al., A FRIEDLANDER APPROACH TO NOVEL 1,10-PHENANTHROLINES AND THEIR USE ASLIGANDS FOR RU(II) AND CU(I), Tetrahedron, 50(36), 1994, pp. 10685-10692
Citations number
16
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron → ACNP
ISSN journal
00404020
Volume
50
Issue
36
Year of publication
1994
Pages
10685 - 10692
Database
ISI
SICI code
0040-4020(1994)50:36<10685:AFATN1>2.0.ZU;2-T
Abstract
A six step synthesis of 8-amino-7-quinolinecarbaldehyde from 8-hydroxy quinoline has been developed. This aminoaldehyde undergoes Friedlander condensation with ketones to form 2-substituted 1,10-phenanthrolines and 1,2-diketones to form 2,2'-bi-(1,10-phenanthroline)s. A tetramethy lene derivative of the latter class of compounds forms a helical dinuc lear complex with Cu(I).