PERFLUOROACYLATION OF ALKENES

Authors
NENAJDENKO VG GRIDNEV ID BALENKOVA ES
Citation
Vg. Nenajdenko et al., PERFLUOROACYLATION OF ALKENES, Tetrahedron, 50(37), 1994, pp. 11023-11038
Citations number
25
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron → ACNP
ISSN journal
00404020
Volume
50
Issue
37
Year of publication
1994
Pages
11023 - 11038
Database
ISI
SICI code
0040-4020(1994)50:37<11023:POA>2.0.ZU;2-T
Abstract
Reaction of direct electrophilic perfluoroacylation of diffferent stru cture alkenes with trifluoroacetic anhydride activated by BF3.SMe(2) c omplex leads to trifluoromethylalkenylketones with different structure of alkenyl group. Possible composition of the reactive species is con sidered on the basis of IR and NMR data. Dependence of the reaction co urse on the substrate structure is discussed.