FLUOROVINYLATION OF ALDEHYDES AND KETONES USING ENYLMETHYLSILYL)-1-FLUORO-1-(PHENYLSULFONYL)ETHANE

Authors
FUJII A USUKI Y IIO H TOKOROYAMA T
Citation
A. Fujii et al., FLUOROVINYLATION OF ALDEHYDES AND KETONES USING ENYLMETHYLSILYL)-1-FLUORO-1-(PHENYLSULFONYL)ETHANE, Synlett, (9), 1994, pp. 725-726
Citations number
22
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Synlett → ACNP
ISSN journal
09365214
Issue
9
Year of publication
1994
Pages
725 - 726
Database
ISI
SICI code
0936-5214(1994):9<725:FOAAKU>2.0.ZU;2-D
Abstract
The carbanion derived from the title beta-silylsulfone reacts with ald ehydes and ketones readily to afford fluoro olefins, which was produce d via desulfination of initially formed adducts with concomitant 1,4-m igration of the diphenylmethylsilyl group from the carbon to the oxyge n atom.