MeV transmission ion channeling has been used to investigate the struc
ture of 0.95 ML of Sb deposited on 0.81 ML of Ge grown pseudomorphical
ly on the Si(100) surface. It is shown that the sb overlayer is compos
ed of asymmetric dimers, in contrast to the symmetric dimers reported
in the literature on the Sb-terminated clean Si(100) surface. It is fu
rther shown that the Ge reconstruction is lifted upon Sb deposition an
d Ge then occupies a near-bulk site. The characterization of the under
lying Ge layer provides additional and convincing evidence for Sb dime
r asymmetry.