FREE-RADICAL METHODOLOGY FOR CARBOHYDRATE TO CARBOCYCLE TRANSFORMATIONS - AN EFFICIENT SYNTHESIS OF THE TRICYCLIC DIHYDROFURAN PORTION OF AZADIRACHTIN

Authors
HENRY KJ FRASERREID B
Citation
Kj. Henry et B. Fraserreid, FREE-RADICAL METHODOLOGY FOR CARBOHYDRATE TO CARBOCYCLE TRANSFORMATIONS - AN EFFICIENT SYNTHESIS OF THE TRICYCLIC DIHYDROFURAN PORTION OF AZADIRACHTIN, Journal of organic chemistry, 59(18), 1994, pp. 5128-5129
Citations number
15
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Journal of organic chemistry → ACNP
ISSN journal
00223263
Volume
59
Issue
18
Year of publication
1994
Pages
5128 - 5129
Database
ISI
SICI code
0022-3263(1994)59:18<5128:FMFCTC>2.0.ZU;2-V
Abstract
Iodo lactone 6b, derived from D-galactal, undergoes tin hydride mediat ed transannular radical cyclization to give the tricyclic lactone 7, w hich is easily converted into an advanced precursor of the tricyclic d ihydrofuran portion of the potent insect antifeedant azadirachtin (1).