STEREOCHEMICAL STUDIES ON THE ADDITION OF ALLYLSILANES TO ALDEHYDES -THE S-E' COMPONENT

Authors
DENMARK SE ALMSTEAD NG
Citation
Se. Denmark et Ng. Almstead, STEREOCHEMICAL STUDIES ON THE ADDITION OF ALLYLSILANES TO ALDEHYDES -THE S-E' COMPONENT, Journal of organic chemistry, 59(18), 1994, pp. 5130-5132
Citations number
61
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Journal of organic chemistry → ACNP
ISSN journal
00223263
Volume
59
Issue
18
Year of publication
1994
Pages
5130 - 5132
Database
ISI
SICI code
0022-3263(1994)59:18<5130:SSOTAO>2.0.ZU;2-2
Abstract
Compounds (l)-1 and (u)-1 have revealed both the position of the silic on electrofuge and the relative orientation of the double bonds in the allylmetal-aldehyde addition. Cyclization was found to proceed with h igh selectivity via an anti SEI pathway regardless of the proximal/dis tal ratio.