HIGHLY SYN-SELECTIVE ADDITIONS OF ALLYLIC STANNANES TO PROTECTED ALPHA-AMINO ALDEHYDES

Authors
MARSHALL JA SELETSKY BM COAN PS
Citation
Ja. Marshall et al., HIGHLY SYN-SELECTIVE ADDITIONS OF ALLYLIC STANNANES TO PROTECTED ALPHA-AMINO ALDEHYDES, Journal of organic chemistry, 59(18), 1994, pp. 5139-5140
Citations number
24
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Journal of organic chemistry → ACNP
ISSN journal
00223263
Volume
59
Issue
18
Year of publication
1994
Pages
5139 - 5140
Database
ISI
SICI code
0022-3263(1994)59:18<5139:HSAOAS>2.0.ZU;2-L
Abstract
The gamma-oxygenated allylic stannane (R)-8b adds to the threonine- an d serine-derived N-BOC aldehydes 1 and 14 in the presence of MgBr2 to afford the syn adducts 9b and 15b as the sole products.