SI-SUBSTITUTED 8-QUINOLYLTHIOMETHYLSILANES

Authors
VORONKOV MG CHERNOV NF TROFIMOVA OM OVCHINNIKOV YE STRUCHKOV YT GAVRILOVA GA
Citation
Mg. Voronkov et al., SI-SUBSTITUTED 8-QUINOLYLTHIOMETHYLSILANES, Russian chemical bulletin, 42(4), 1993, pp. 725-729
Citations number
11
Categorie Soggetti
Chemistry
Journal title
Russian chemical bulletin → ACNP
ISSN journal
10665285
Volume
42
Issue
4
Year of publication
1993
Pages
725 - 729
Database
ISI
SICI code
1066-5285(1993)42:4<725:S8>2.0.ZU;2-8
Abstract
(8-Quinolylthiomethyl)trimethoxy- and methyl(8-quinolylthiomethyl)dime thoxysilanes were synthesized and transformed into the corresponding o rganyltrifluoro- and methyldifluorosilanes. IR spectroscopy revealed t he absence of N --> Si donor-acceptor interaction in (8-quinolylthiome thyl)trifluorosilane and methyl(8-quinolylthiomethyl)difluorosilane. T ransesterification of (8-quinolylthiomethyl)trimethoxysilane with trie thanolamine yielded 1-(8-quinolylthiomethyl)silatrane; the crystal and molecular structures of the latter were determined by X-ray study.