VISCOELASTICITY OF LYOTROPIC SMECTICS

Authors
Citation
Cyd. Lu et Me. Cates, VISCOELASTICITY OF LYOTROPIC SMECTICS, The Journal of chemical physics, 101(6), 1994, pp. 5219-5228
Citations number
36
Categorie Soggetti
Physics, Atomic, Molecular & Chemical
ISSN journal
00219606
Volume
101
Issue
6
Year of publication
1994
Pages
5219 - 5228
Database
ISI
SICI code
0021-9606(1994)101:6<5219:VOLS>2.0.ZU;2-3
Abstract
We study theoretically the contribution of thermal fluctuations to the linear theological spectrum of lyotropic smectic A phases at low freq uencies. The fluctuations are treated at the Gaussian level; their hyd rodynamics is controlled by the undulation/baroclinic mode. In the lay er-over-layer sliding geometry, we find an anomalous elasticity varyin g as /omega/; the corresponding viscous drag is enhanced logarithmical ly. For other shear geometries we find contributions to the dissipatio n and elasticity that are in practice small (though formally divergent when the layer spacing is taken to zero). The connection between thes e results and those given previously for thermotropic smectics, and fo r block copolymers, is discussed. We outline the possible experimental significance of our findings for the rheology of both aligned and pol ydomain smectics.