HYDROGEN-BONDING IN ORGANOMETALLIC CRYSTALS .1. FROM CARBOXYLIC-ACIDSAND ALCOHOLS TO CARBONYL-COMPLEXES

Authors
BRAGA D GREPIONI F SABATINO P DESIRAJU GR
Citation
D. Braga et al., HYDROGEN-BONDING IN ORGANOMETALLIC CRYSTALS .1. FROM CARBOXYLIC-ACIDSAND ALCOHOLS TO CARBONYL-COMPLEXES, Organometallics, 13(9), 1994, pp. 3532-3543
Citations number
66
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Organometallics → ACNP
ISSN journal
02767333
Volume
13
Issue
9
Year of publication
1994
Pages
3532 - 3543
Database
ISI
SICI code
0276-7333(1994)13:9<3532:HIOC.F>2.0.ZU;2-M
Abstract
The molecular organization in crystals of selected transition metal co mplexes and clusters containing hydrogen bond donor and acceptor group s such as -COOH, -OH, and -COOR as well as CO ligands has been investi gated. Strict analogies have been found between the hydrogen bonding p atterns in the organometallic crystals and those present in the corres ponding organic crystals. It has been possible to show that CO partici pates in hydrogen bonding when other stronger accepters are not in com petition.