SITE-SELECTIVE SIGMA-BOND METATHESIS REACTIONS OF SC(CD3)(2)(-D-2]PROPANE, [1,1,1,4,4,4-D-6]-N-BUTANE, AND [2-D]ISOBUTANE() WITH [2,2)

Authors
CRELLIN KC GERIBALDI S BEAUCHAMP JL
Citation
Kc. Crellin et al., SITE-SELECTIVE SIGMA-BOND METATHESIS REACTIONS OF SC(CD3)(2)(-D-2]PROPANE, [1,1,1,4,4,4-D-6]-N-BUTANE, AND [2-D]ISOBUTANE() WITH [2,2), Organometallics, 13(9), 1994, pp. 3733-3736
Citations number
22
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Organometallics → ACNP
ISSN journal
02767333
Volume
13
Issue
9
Year of publication
1994
Pages
3733 - 3736
Database
ISI
SICI code
0276-7333(1994)13:9<3733:SSMROS>2.0.ZU;2-J
Abstract
Fourier transform ion cyclotron resonance mass spectrometry is used to show that Sc(CD3)(2)+ reacts with saturated alkanes larger than ethan e in the gas phase by a four center a-bond metathesis reaction, with m ethane elimination. These processes are facile at room temperature, in volve little or no activation enery, and occur preferentially with pri mary carbon-hydrogen. bonds.