P. Carretta et al., SPIN FLUCTUATIONS IN DOPED ANTIFERROMAGNETS FROM LI-7 NMR RELAXATION IN CUOLI, Physical review. B, Condensed matter, 49(10), 1994, pp. 7044-7047
Li-7 NMR relaxation is used to derive information on the low-energy sp
in excitations induced in antiferromagnetic (AF) CuO by the heterovale
nt substitution of one percent of Cu2+ by Li+. The energy gap E(g) bet
ween localized and itinerant states, where the extra hole diffuses in
the AF matrix, is obtained as E(g) congruent-to 600 K while the effect
ive correlation time of the hole is tau(h) congruent-to (1/omega(exch)
/xe(-E(g)/T), in agreement with the main conclusions of a previous wor
k in Cu1-xLixO for larger doping [P. Carretta, M. Corti, and A. Rigamo
nti, Phys. Rev. B 48, 3433 (1993)]. The experimental findings are disc
ussed in comparison with the ones in lightly doped AF La2-xSrxCuO4, wh
ere a drastic changeover in the x dependence of the spin fluctuation p
roperties has been recently found for x less than or similar to 0.02 [
F. C. Chou et al., Phys. Rev. Lett. 71, 2323 (1993)]. Finally, mostly
on the basis of Li-7 relaxation rates at different measuring frequenci
es, it is conjectured that in Cu0.99Li0.01O one has a localization of
the extra hole, possibly in the CuO4 plaquette [R. J. Gooding, Phys. R
ev. Lett. 66, 2266 (1991)], establishing a condition of fast spin fluc
tuations.