THE ROLE OF NONPOLAR INTERACTIONS IN THE REACTIONS OF NONSTOICHIOMETRIC INTERPOLYELECTROLYTE COMPLEXES WITH ANIONIC SURFACTANTS

Authors
KOROBKO TA IZUMRUDOV VA ZEZIN AB KABANOV VA
Citation
Ta. Korobko et al., THE ROLE OF NONPOLAR INTERACTIONS IN THE REACTIONS OF NONSTOICHIOMETRIC INTERPOLYELECTROLYTE COMPLEXES WITH ANIONIC SURFACTANTS, Vysokomolekularnye soedinenia. Seria A, 36(2), 1994, pp. 223-228
Citations number
15
Categorie Soggetti
Polymer Sciences
Journal title
Vysokomolekularnye soedinenia. Seria A → ACNP
ISSN journal
05075475
Volume
36
Issue
2
Year of publication
1994
Pages
223 - 228
Database
ISI
SICI code
0507-5475(1994)36:2<223:TRONII>2.0.ZU;2-2
Abstract
The competing reactions of substitution of polyanion of sodium polymet hacrylate, which is involved in water-soluble nonstoichiometric interp olylectrolyte complex containing alkylated poly(4-vinyl pyridinium cat ion), with anionic surfactants (sodium caprate, sodium dodecyl sulfate ) were studied by luminescence quenching technique. Equilibrium of the competing reactions was shown to be primarily controlled by the chemi cal nature of polycation, in particular, by the presence of hydrophobi c N-alkyl substituents in polycation chain.