CU3BI4V2O14, A NEW COMPOUND

Authors
DEACON GB GATEHOUSE BM WARD GN
Citation
Gb. Deacon et al., CU3BI4V2O14, A NEW COMPOUND, Acta crystallographica. Section C, Crystal structure communications, 50, 1994, pp. 1178-1180
Citations number
11
Categorie Soggetti
Crystallography
Journal title
Acta crystallographica. Section C, Crystal structure communications → ACNP
ISSN journal
01082701
Volume
50
Year of publication
1994
Part
8
Pages
1178 - 1180
Database
ISI
SICI code
0108-2701(1994)50:<1178:CANC>2.0.ZU;2-9
Abstract
The title compound has an infinite three-dimensional structure that co ntains eight-coordinate bismuth(III), five- and six-coordinate copper( II) and four-coordinate vanadium(V). The mean bond distances are: Bi-O 2.57(31) Angstrom, Cu-O 1.956(27)(in the square planes), 2.64 (10) A (out-of-plane distances), and V-O 1.713 (29) Angstrom. The shortest Cu -Cu distance is 3.063 (3) Angstrom.