BIS(TERT-BUTYLAMMONIUM) MOLYBDATE(VI)

Authors
ROMAN P JOSE AS LUQUE A GUTIERREZZORRILLA JM MARTINEZRIPOLL M
Citation
P. Roman et al., BIS(TERT-BUTYLAMMONIUM) MOLYBDATE(VI), Acta crystallographica. Section C, Crystal structure communications, 50, 1994, pp. 1189-1191
Citations number
29
Categorie Soggetti
Crystallography
Journal title
Acta crystallographica. Section C, Crystal structure communications → ACNP
ISSN journal
01082701
Volume
50
Year of publication
1994
Part
8
Pages
1189 - 1191
Database
ISI
SICI code
0108-2701(1994)50:<1189:BM>2.0.ZU;2-T
Abstract
During the course of our extensive studies on the molybdenum-tert-buty lamine base system, we isolated the title compound, [C4H12N](2)[MoO4], by reaction of stoichiometric amounts of MoO3 and ter t-butylamine in aqueous media. The asymmetric unit of di-tert-butylammonium molybdate (VI) consists of two tetrahedral [MoO4](2-) anions and four tert-butyl ammonium cations. The crystal packing is stabilized by the electrostat ic interactions and an extensive network of hydrogen contacts involvin g the O atoms from the anions, and the N atoms and some C atoms of the cations.