IS-AMMINE(BENZOYLHYDRAZINE-N)-DICHLOROPLATINUM(II)

Authors
MACICEK J DODOFF N SPASSOVSKA N
Citation
J. Macicek et al., IS-AMMINE(BENZOYLHYDRAZINE-N)-DICHLOROPLATINUM(II), Acta crystallographica. Section C, Crystal structure communications, 50, 1994, pp. 1214-1217
Citations number
11
Categorie Soggetti
Crystallography
Journal title
Acta crystallographica. Section C, Crystal structure communications → ACNP
ISSN journal
01082701
Volume
50
Year of publication
1994
Part
8
Pages
1214 - 1217
Database
ISI
SICI code
0108-2701(1994)50:<1214:I>2.0.ZU;2-H
Abstract
In the title compound, is-ammine(benzohydrazide-N')-dichloroplatinum(I I), cis-[PtCl2(C7H8N2O)(NH3)], the benzoylhydrazine ligand is bonded t o the Pt atom through its amino group. The Pt-Cl and Pt-N distances ar e in the ranges 2.293 (5)-2.318 (5) and 2.01 (1)-2.08 (1) Angstrom, re spectively. The arrangement of molecules in the monoclinic unit cell a pproximates P2(1)/c space-group patterns; however, the true space-grou p symmetry is P2(1). The two crystallographically independent molecule s have significantly different conformations about the Pt-N(hydrazine) bond. The structure is held together by a complicated network of N-H. ..O and N-H...Cl hydrogen bonds.