CETAMIDE-S)-BIS(TRIPHENYLPHOSPHINE-P)RUTHENIUM(II) TETRAFLUOROBORATE

Authors
BRYAN CD CORDES AW DRAGANJAC M
Citation
Cd. Bryan et al., CETAMIDE-S)-BIS(TRIPHENYLPHOSPHINE-P)RUTHENIUM(II) TETRAFLUOROBORATE, Acta crystallographica. Section C, Crystal structure communications, 50, 1994, pp. 1231-1233
Citations number
6
Categorie Soggetti
Crystallography
Journal title
Acta crystallographica. Section C, Crystal structure communications → ACNP
ISSN journal
01082701
Volume
50
Year of publication
1994
Part
8
Pages
1231 - 1233
Database
ISI
SICI code
0108-2701(1994)50:<1231:CT>2.0.ZU;2-T
Abstract
The title compound [Ru(C5H5)(C2H5NS)(C18H15P)(2)]-BF4 crystallizes in the space group P2(1)/c. The Ru atom has pseudotetrahedral coordinatio n geometry formed by the cyclopentadienyl centroid, the two PPh(3) lig ands and the 5 atom of the neutral thioacetamide molecule. The Ru-S an d C=S distances are 2.3820 (13) and 1.671 (5) Angstrom, respectively, and the Ru-S=C angle is 116.3 (2)degrees. The Ru atom is at a distance of 0.405 (9) Angstrom from the plane formed by the atoms of the thioa cetamide group.