[AU((N)BUPPH(2))((PH(2)PS)(3)C)]CENTER-DOT-CH3CN - AN IRREGULAR 3-COORDINATE AU-1 COMPLEX

Authors
STAPLES RJ WANG SN FACKLER JP GRIM SO DELAUBENFELS E
Citation
Rj. Staples et al., [AU((N)BUPPH(2))((PH(2)PS)(3)C)]CENTER-DOT-CH3CN - AN IRREGULAR 3-COORDINATE AU-1 COMPLEX, Acta crystallographica. Section C, Crystal structure communications, 50, 1994, pp. 1242-1244
Citations number
8
Categorie Soggetti
Crystallography
Journal title
Acta crystallographica. Section C, Crystal structure communications → ACNP
ISSN journal
01082701
Volume
50
Year of publication
1994
Part
8
Pages
1242 - 1244
Database
ISI
SICI code
0108-2701(1994)50:<1242:[-AI3>2.0.ZU;2-I
Abstract
The molecule of e-P][tris-(diphenylthiophosphinoyl)methanido-S,S'] gol d(I) consists of an n-butyldiphenylphosphine ligand coordinated to the Au-I center with a normal Au-P distance [2.275 (4) Angstrom], and a t ris(diphenylthiophosphinoyl)methanide ligand coordinated to the Au-I c enter through two of the S atoms with two strikingly different Au-S di stances [2.326 (4) and 2.894 (4) Angstrom]. The Au-I center has T-shap ed coordination geometry.