BENZYL(BROMO)DIPHENYLLEAD

Authors
FAHRENKAMPF U SCHURMANN M HUBER F
Citation
U. Fahrenkampf et al., BENZYL(BROMO)DIPHENYLLEAD, Acta crystallographica. Section C, Crystal structure communications, 50, 1994, pp. 1252-1254
Citations number
11
Categorie Soggetti
Crystallography
Journal title
Acta crystallographica. Section C, Crystal structure communications → ACNP
ISSN journal
01082701
Volume
50
Year of publication
1994
Part
8
Pages
1252 - 1254
Database
ISI
SICI code
0108-2701(1994)50:<1252:B>2.0.ZU;2-3
Abstract
The coordination polyhedron around Pb in the title compound, [PbBr(C6H 5)(2)(C7H7)], is a slightly distorted trigonal bipyramid, the trigonal plane being formed by the C(Pb) atoms of the three organic ligands. T he axial positions are occupied by Br atoms [Pb(1)-Br(1) 2.985 (2), Pb (1)-Br(1a) 2.885 (2) Angstrom], each Br atom bridging neighbouring mol ecules to form infinite Br(1a)-Pb(1)-Br(1)-Pb(1b) chains [Br(1a)-Pb(1) -Br(1) 173.610 (15), Pb(1)-Br(1)-Pb(1b) 122.73 (5)degrees], i.e. caten a-poly-[(benzyldiphenyllead)-mu-bromo].