STUDY OF ACTIVITY DISTRIBUTION FOR CONSECUTIVE REACTIONS

Citation
Z. Letkova et al., STUDY OF ACTIVITY DISTRIBUTION FOR CONSECUTIVE REACTIONS, Collection of Czechoslovak Chemical Communications, 59(8), 1994, pp. 1788-1799
Citations number
10
Categorie Soggetti
Chemistry
ISSN journal
00100765
Volume
59
Issue
8
Year of publication
1994
Pages
1788 - 1799
Database
ISI
SICI code
0010-0765(1994)59:8<1788:SOADFC>2.0.ZU;2-A
Abstract
The optimal pellet activity distribution for a system of consecutive r eactions is analyzed numerically. Two cases are studied: the case of u nconstrained activity (without predescribed maximal concentration of a ctive component) leading to a Dirac delta activity distribution and th e case with upper bound for the activity distribution (concentration o f active component can not exceed given maximal value) which leads to a step function profile. As the objective function global selectivity is chosen. Examples of both cases are given. The reaction kinetics is described by Langmuir-Hinshelwood type of equations.