Mn. Rao et al., SYNTHESIS OF HENYL-9H-PYRANO[2,3-G]BENZOTHIAZOL-2-YL)BENZAMIDES FROM 6-AMINOFLAVONE, Bulletin of the Chemical Society of Japan, 67(8), 1994, pp. 2326-2328
6-Aminoflavone1) (1) was treated with aroyl isothiocyanate in acetone
at reflux temperature yields N'-(2-phenyl-4-oxo-4H-[1]benzopyran-6-yl)
thioureas (2). The products obtained on reaction of 2 with PCl5 in POC
l3 medium leads to henyl-9H-pyrano[2,3-g]benzothiazol-2-yl)benzamides
(4). The structures of the compounds synthesized were established by a
nalytical and spectral data.