MORPHOLOGY OF ULTRAFINE RUO2-IRO2 BINARY OXIDE PARTICLES PREPARED BY A SOL-GEL PROCESS

Citation
Y. Murakami et al., MORPHOLOGY OF ULTRAFINE RUO2-IRO2 BINARY OXIDE PARTICLES PREPARED BY A SOL-GEL PROCESS, Journal of the Electrochemical Society, 141(9), 1994, pp. 120000118-120000120
Citations number
13
Categorie Soggetti
Electrochemistry
ISSN journal
00134651
Volume
141
Issue
9
Year of publication
1994
Pages
120000118 - 120000120
Database
ISI
SICI code
0013-4651(1994)141:9<120000118:MOURBO>2.0.ZU;2-S
Abstract
Ultrafine particles of RuO2-IrO2 binary oxides with various compositio ns of Ru and Ir have been prepared by a sol-gel process consisting of hydrolysis and condensation of metal ethoxide ethanol solutions. The ( Ru, Ir)O2 rutile-type solid solution of binary oxides was formed. High -resolution scanning electron micrographs of the Ru-Ir binary oxides s howed the spherical-like crystallites for Ru-rich oxides and needle-li ke ones for Ir-rich oxides. The particle size was the smallest for the binary oxide with comparable Ru-Ir composition.