Y. Murakami et al., MORPHOLOGY OF ULTRAFINE RUO2-IRO2 BINARY OXIDE PARTICLES PREPARED BY A SOL-GEL PROCESS, Journal of the Electrochemical Society, 141(9), 1994, pp. 120000118-120000120
Ultrafine particles of RuO2-IrO2 binary oxides with various compositio
ns of Ru and Ir have been prepared by a sol-gel process consisting of
hydrolysis and condensation of metal ethoxide ethanol solutions. The (
Ru, Ir)O2 rutile-type solid solution of binary oxides was formed. High
-resolution scanning electron micrographs of the Ru-Ir binary oxides s
howed the spherical-like crystallites for Ru-rich oxides and needle-li
ke ones for Ir-rich oxides. The particle size was the smallest for the
binary oxide with comparable Ru-Ir composition.