Jh. Bulloch et Jj. Hickey, SOME OBSERVATIONS CONCERNING REVERSE TEMPER EMBRITTLEMENT AND CREEP DAMAGE IN A SERIES OF CRMOV STEEL TURBINE BOLTS AFTER 120000 H OF SERVICE, Materials at high temperatures, 12(1), 1994, pp. 13-24
This paper describes a detailed investigation which was specifically a
imed at providing a simple practical assessment procedure which identi
fied reverse temper embrittlement (RTE) in a series of high-pressure (
HP) and intermediate-pressure (IP) CrMoV steel turbine bolts from two
separate 120 MW sister units which had been subjected to 120 000 h of
service. A small section of material was removed from a noncritical lo
cation from all 182 bolts. From this section the chemical composition,
average hardness and prior austenite grain size were assessed. The to
ughness of selected bolts was measured by either (i) Charpy impact tes
ting or (ii) Auger electron spectroscopy. It was established that grai
n size and bulk phosphorus content were the primary factors which cons
istently correlated with the embrittled condition. An embrittlement es
timative diagram was established by plotting grain size d versus perce
ntage phosphorus. This portrayed two distinct regions, namely on embri
ttled region and a non-embrittled region, which were separated by a cr
itical interface which could be described by the expression d(% P) = C
where C is a constant. The value of C is, however, strongly dependent
upon the level of accumulated bolt strain during service. Indeed, the
higher the value of average bolt strain E(AV), the smaller the numeri
cal value of C, i.e. with increasing E(AV) embrittlement was promoted
in bolts with finer grain sizes and lower phosphorus levels. Indeed, i
t was projected that at E(AV) = 0.5% nearly all the bolts in the prese
nt investigation would have undergone embrittlement. From a creep dama
ge assessment conducted on a selection of bolts in the thread root loc
ation was observed that, at average strain levels, aproaching 0.5%, bo
lts with grain sizes of about 20 mum will have suffered RTE and a meas
urable amount of secondary creep damage. The limited amount of data su
ggested that, for coarser grain sizes, creep damage or grain boundary
cavitation occurred at lower accumulated strains. Finally it was shown
that, in the few instances where secondary creep damage was recorded,
the accumulated strain at the thread root location was 2.7 times high
er than the average bolt strain E(AV) obtained by bolt length measurem
ents.