S. Konosu, SIMPLIFIED ASSESSMENT OF HYDROGEN ACCUMULATION AT STAINLESS-STEEL OVERLAY BOUNDARIES OF HIGH-TEMPERATURE, HIGH-PRESSURE HYDROGEN REACTORS, Materials at high temperatures, 12(1), 1994, pp. 47-51
With regard to the cracking (disbonding) which occurs at the fusion bo
undary of austenitic overlays and the base metal of high-temperture, h
igh-pressure hydrogen reactors, the accumulation of hydrogen at the fu
sion boundaryu subsequent to cooling from a high to a normal temperatu
re, which is considered to be the largest causative factor of such cra
cking, has been evaluated by numerically solving diffusion equations u
sing differential calculus. It has been shown that the amount of accum
ulated hydrogen cna be expressed by applying a simple, approximate for
mula which incorporates the service pressure of the hydrogen, service
temperature, thickness of overlay and base metal, cooling rate, hydrog
en solubility, and hydrogen diffusion coefficients.