EXPLOSION OF TETRAFLUOROETHYLENE DURING NONISOTHERMAL POLYMERIZATION

Authors
BABENKO YI LISOCHKIN YA POZNYAK VI
Citation
Yi. Babenko et al., EXPLOSION OF TETRAFLUOROETHYLENE DURING NONISOTHERMAL POLYMERIZATION, Combustion, explosion, and shock waves, 29(5), 1993, pp. 603-609
Citations number
8
Categorie Soggetti
Engineering,Thermodynamics
Journal title
Combustion, explosion, and shock waves → ACNP
ISSN journal
00105082
Volume
29
Issue
5
Year of publication
1993
Pages
603 - 609
Database
ISI
SICI code
0010-5082(1993)29:5<603:EOTDNP>2.0.ZU;2-T
Abstract
On the basis of dimerization kinetics and experimental data on thermal explosion we determine conditions for ignition of tetrafluoroethylene on a hot wall. A mathematical model of nonisothermal polymerization o n a plane wall and in a cavity which takes into account heat removal t o the wall and to the gas phase is proposed. The conditions for explos ion hazard situations are established and expressions for the inductio n time are obtained.