The first part of this paper presents the preparation and morphologica
l studies of high surface area polypyrrole with fibrillar morphology.
Mode of fibre growth within host membrane pores has been examined by u
ltra-microtome techniques. The rate of fibre growth in different solve
nts has been determined. The second part of this paper describes the f
ormation of conducting composite membranes of polypyrrole with in-hous
e prepared and commercial (''Biotran'') microporous polyamides. The co
nducting polymer was chemically polymerized using several techniques i
n association with the membranes in these studies. Surface and cross-s
ectional membrane morphology was studied by high-resolution field emis
sion scanning electron microscopy, optical microscopy and transmission
electron microscopy. Environmental stability of composite membranes h
as been examined by measuring the conductivity as a function of time.